The distributor is an easy upgrade and since you would probably be adjusting points and timing anyway it sounds like a good time to do it. Make sure you get/have the right mount; the 240/260 dizzy has the screws way off from the 280zx. Here is a nice little write-up: http://www.atlanticz.ca/zclub/techtips/distributor/index.html
I'd try to check and/or replace as many fluids and as much rubber as possible before you go, and bring some extra with you. The accessory belts are easy to replace and likely to be old/worn. Obviously make sure the fuel lines are safe, especially the ones that were added/changed with the Holley. Speaking of changed lines for the Holley... Check to see how the brake booster is connected to vacuum and that it has a (working) check-valve. The PCV system might be hacked as well so check the block vent and make sure it isn't capped, a breather isn't ideal but at least you won't blow a seal. Something that may or may not need to be addressed are the shifter bushings, 40 year old plastic tends to disappear but there is a brass option (http://www.atlanticz.ca/zclub/techtips/shifterbushing/index.html)
based on my experience... then research it isn't uncommon for the ignition switch or combo-switch to go out and cause starting or electrical problems, some wire and a momentary switch are a short term fix - I'm not endorsing that as a permanent solution but if you really want to make it home a little ugly might just get you there.
Regarding spares... other than your spare tire, jack, tools... wheel locks? A healthy supply of fuses, electrical tape, zip-ties, bailing wire (aka, custom exhaust hanger), maybe some duct tape, and some road flares. I'd bring the old belts, spare hose, extra clamps, and all the common fluids as well as at least a few gallons of water. If the car overheats -water for the car, if you break down in the heat - life sustaining moisture for you. Snacks are good too, you can have a picnic on the side of the freeway if things go South but if you plan ahead you shouldn't need to.
I'd highly recommend using/borrowing/getting a GPS to accurately tell your speed and give you directions.
Since you will be driving over at least one mountain range and across some desert on you epic journey I'd bring plenty of water and check/replace the thermostat as well as do some serious flushing of the whole cooling system.
One last piece of advice; install a disconnect or just unhook the battery if you stop overnight. It isn't like you are going to reset your ECU and a lot of old cars have power drains that could leave you with a dead battery in the morning.
I'm surprised that nobody else has chimed in on this, you might want to search or create a new thread for more advice.