"Shut up, you're being infantile", ???? Well that's much more mature. What YOU said quite clearly is that SS is so thermally efficient that it doesn't require any additional thermal barrier. Also, it won't degrade like mild steel. Define degrade? Clearly it's not going to corrode away like mild steel would after numerous heat cycles , but it will most certainly oxidize and look like hell rather quickly. I've just shown you 3 normally aspirated examples of uncoated SS components and they look like hell. The turbo stuff looks even worse. Further, you have no idea why Bloz is even entertaining the idea of ceramic coating his headers. You've made the assumption its for thermal management concerns when it could be purely for aesthetic purposes, If it is for thermal management concerns, your heat shield does nothing for reducing temperatures or making the headers more thermally efficient, it merely insulates the radiated heat from affecting a particular part or area, i.e. delicate wires or electronics.
As for temperature, its rather pointless to regurgitate the specific thermal properties of any given grade of SS or mild steel in that you have no idea what material he is using and what the wall thickness is. The most thermally efficient SS is going to be less effective than the lesser performing mild steel if the mild steel has a significantly thicker wall. As a rather large generalization, there is no argument that SS is more thermally efficient, than said mild steel, BUT......... the problem with SS is that once its hot it acts like a huge heat sink much like a cast iron manifold. It retains and radiates a significant amount of heat off of it surface.
In 15+ years of dealing with exhaust systems ranging from OE manifolds to 5000HP plus twin turbo shoot out cars I have never heard from anyone that changed from a mild steel exhaust to a SS exhaust and said their under hood temps went down...... On the contrary, guys with mid-engine cars like the earlier mentioned Ferrari F430 and panteras see an IMMEDIATE increase both underhood / cabin temperature from upgrading to SS exhaust....