You can weld stainless with a mild steel wire. The problem is you loose the properties of the stainless, so if corosion resistance is what your looking for its not a good idea.....I assume its for exhaust piping, if so it will hold for sure as long as fusion is all your looking for......Otherwise get a stainless wire, wich could be expensive, possibly hard to find in smaller dia, also could be hard to weld on thinner material.....If you go the route of stainless wire, use a 75% argon 25% CO2 gas and it should weld nicely......I dont think a back purge would be needed for exhaust piping....