Heavy porting and bigger valves are generally for higher rpm and more compression then what you are planning. I would try the 300 duration, .525 lift cam since you already have it and install the bigger valves. It should be good from 4,000 to 7,000. You'll need to change your rear gears (depending on tire size)
If you already have the parts, might as well use them. You might find you like more power up top.