I will attempt to answer your question about octane. A higher octane will resist detonation (uncontrolled burning) more than a lower octane. This will allow you to run your optimum ignition timing for your engine's compression and boost level. That is what can give you more power with higher octane fuel - a Z car generally have a set ignition curve, and if it's set to handle a lower octane without detonation, you will not benefit from higher octane.
Search archives here - there are some excellent links on this subject that explain exactly what detonation is and what you can do to mitigate it.
By itself, the octane will not "increase boost". That sounds like a function of your boost controller's inability to manage a constant boost level under different load conditions. And be careful with your POV shims. You will add another shim and the valve will be wedged shut, or have so little flow area to be any use. You'd be much better off just plugging it, or adding another or stiffer spring inside so you still have the valve travel.