You should have no problem passing emissions with an intercooler, which is before the fuel/air mixture part of controlling the engine.
It has the added benefit of taking thermal stress off the engine.
I personally wouldn't contemplate H2O or methanol injection until I got over 15 lbs of boost.
THe main reson for this attitue is that up to 15 lbs boost, assuming that one has an adequate I/C, yuou DON'T NEED anything else.
Without the I/C, you are somewhat limited in how much boost, and even if you use some gorm of liquid injection, you have to be sure you DON'T RUN OUT of the cooling liquid.